The Nature of the Mechanical Bond (gnv64)


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The Nature of the Mechanical Bond
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Books : Educational : English


The Nature of the Mechanical Bond: From Molecules to Machines
By Carson J. Bruns and J. Fraser Stoddart
Wiley | November 2016 | ISBN-10: 1119044006 | 786 Pages | PDF | 149 mb

https://www.amazon.com/Nature-Mechanical-Bond-Molecules-Machines/dp/1119044006

In molecules, the mechanical bond is not shared between atoms-it is a bond that arises when molecular entities become entangled in space. Just as supermolecules are held together by supramolecular interactions, mechanomolecules, such as catenanes and rotaxanes, are maintained by mechanical bonds. This emergent bond endows mechanomolecules with a whole suite of novel properties relating to both form and function. They hold unlimited promise for countless applications, ranging from their presence in molecular devices and electronics to their involvement in remarkably advanced functional materials. The Nature of the Mechanical Bond is a comprehensive review of much of the contemporary literature on the mechanical bond, accessible to newcomers and veterans alike. Topics covered include:
- Supramolecular, covalent, and statistical approaches to the formation of entanglements that underpin mechanical bonds in molecules and macromolecules
- Kinetically and thermodynamically controlled strategies for synthesizing mechanomolecules
- Chemical topology, molecular architectures, polymers, crystals, and materials with mechanical bonds
- The stereochemistry of the mechanical bond (mechanostereochemistry), including the novel types of dynamic and static isomerism and chirality that emerge in mechanomolecules
- Artificial molecular switches and machines based on the large-amplitude translational and rotational motions expressed by suitably designed catenanes and rotaxanes.
This contemporary and highly interdisciplinary field is summarized in a visually appealing, image-driven format, with more than 800 illustrations covering both fundamental and applied research. The Nature of the Mechanical Bond is a must-read for everyone, from students to experienced researchers, with an interest in chemistry's latest and most non-canonical bond.

About the Authors

J. Fraser Stoddart was born in the capital of Scotland on Victoria Day (May 24) in 1942. By contributing to the introduction of the mechanical bond into molecules, he has become one of the few chemists to have opened up an entirely new field of chemistry. He shares the 2016 Nobel Prize in Chemistry with Jean-Pierre Sauvage and Ben Feringa for the design and synthesis of molecular machines. His current research interests include the design and synthesis of emergent systems and artificial molecular machines that operate away-from-equilibrium.

Carson J. Bruns is scientist, writer, and artist based in Berkeley, California, where he is currently a Miller Research Fellow at the University of California. He has a PhD in Chemistry from Northwestern University and a BA in Religion from Luther College. He writes about one of the newest and most unusual bonds in chemistry: the mechanical bond. This "bond" is an entanglement within molecules that is revolutionizing chemistry by allowing researchers to design remarkable materials and molecular machines that will underpin the nanotechnologies of the future.

CONTENTS
Foreword ix
Preface xi
Acknowledgments xiii
About the Authors xiv
Abbreviations, Acronyms, and Symbols xv
Part 1 Introducing Mechanical Bonds 1
1 An Introduction to the Mechanical Bond 3
Part 2 Making Mechanical Bonds 55
2 The Fundamentals of Making Mechanical Bonds 57
3 Making Mechanical Bonds Under Thermodynamic Control 269
Part 3 Cultivating Mechanical Bonds 347
4 Molecular Topologies and Architectures with Mechanical Bonds 349
5 The Stereochemistry of the Mechanical Bond 471
6 Molecular Switches and Machines with Mechanical Bonds 555
Appendix A: Glossary of Terminology 734
Appendix B: Cover Art Gallery 742
Index 753
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